Formation of Water-Bearing Defects in Olivine in the Presence of Water–Hydrocarbon Fluid at 6.3 GPa and 1200°C     

A.?G.?SokolEmail author  I.?N.?Kupriyanov  A.?A.?Tomilenko  T.?A.?Bul’bak  Yu.?N.?Palyanov  N.?V.?Sobolev 《Doklady Earth Sciences》2018,483(1):1451-1453

The main trends of water dissolution in Fe-bearing olivine have been investigated in the olivine–H₂O–hydrocarbon fluid system in experiments at a pressure of 6.3 GPa, a temperature of 1200°C, and hydrogen fugacity ( fH₂) buffered by the Mo–MoO₂ equilibrium. The content and contribution of ОH defects of different types in Fe-bearing olivines depend on the composition of reduced fluids in the system. As the fraction of hydrocarbons in the fluid increases, the H₂O content in olivine crystals decreases from 900 to 160–180 ppm, while the ОН absorption peaks become lower at high frequencies and occupy a larger part of the infrared spectrum in the low-frequency region. According to the experimental results, even the deepest seated mantle olivines with OH defects were not equilibrated with a fluid rich in light alkanes or oxygenated hydrocarbons.  相似文献   

Indicator Isotope–Geochemical Characteristics of Sulfides from the Satka Magnesite Ore Field (South Urals Province)     

Krupenin  M. T.  Michurin  S. V. 《Doklady Earth Sciences》2018,478(1):108-111

The stable enrichment of pyrite from magnesite ores in δ³⁴S isotope (from 5.4 to 6.9‰) compared with pyrite from the host (sedimentary and igneous) rocks was established in the classical Satka sparry magnesite ore field. Concretionary segregations of fine-grained pyrite in dolomite are depleted in the heavy sulfur isotope (δ³⁴S, from–9.1 to–5.8‰). Pyrite from dolerite is characterized by δ³⁴S values (–1.1 and 1.7‰) close to the meteorite sulfur. The δ³⁴S values in barite from the underlying dolomite horizon vary in the range of 32.3–41.4‰. The high degree of homogeneity of the sulfur isotope composition in pyrite from magnesite is a result of thermochemical sulfate reduction during the syngenetic crystallization of pyrite and magnesite from epigenetic brines, formed during dissolution of evaporite sulfate minerals at the stage of early catagenesis of the Riphean deposits.

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Phenanthrene biomarkers in the organic matter of Precambrian and Phanerozoic deposits and in the oils of the Siberian Platform     

V.A. Kashirtsev  T.M. Parfenova  A.K. Golovko  B.L. Nikitenko  I.N. Zueva  O.N. Chalaya 《Russian Geology and Geophysics》2018,59(10):1380-1388

The composition and distribution of phenanthrenes (polyaromatic compounds) have been studied in chloroform extracts from dispersed organic matter (OM) of clayey, siliceous, carbonate, and terrigenous rocks of different ages and facies and from some oils of the Siberian Platform. Phenanthrenes have been analyzed by gas chromatography-mass spectrometry. High contents of 1,7,8-trimethylphenanthrene and 1,1,7,8-tetramethyl-1,2,3,4-tetrahydrophenanthrene are present in the OM of Vendian and Cambrian carbonate-shale deposits and in ancient oils of the Nepa-Botuobiya and Anabar anteclises. The OM of Permian continental deposits and oils of the Vilyui syneclise is dominated by 1-methyl-7-isopropylphenanthrene (retene). A triangular diagram for identification of the types of original OM of rocks and classification of genetically related oils has been constructed based on the assessment of phenanthrene biomarker distribution. Putative pathways of the formation of phenanthrene biomarkers are discussed.  相似文献   

Holocene overbank deposition in the drainage basin of Lake Khanka     

V.B. Bazarova  M.S. Lyashchevskaya  T.R. Makarova  R.A. Makarevich  L.A. Orlova 《Russian Geology and Geophysics》2018,59(11):1410-1418

Overbank deposits in the Komissarovka River valley consist of alternating silt, clay silt, sand, and soils produced by lacustrine, alluvial, and aeolian deposition and by soil formation. Silt and sand layers in the lower part of the section correlate with the events of Early Holocene transgression and Middle Holocene regression of Lake Khanka. Deposition in the lowermost reaches of the Komissarovka River provides a faithful record of local Holocene landscapes controlled by level changes in Lake Khanka.  相似文献   

Isotope stratigraphy and U-Pb dating of detrital zircons from the Vendian-Cambrian deposits of the North Muya block     

I.A. Vishnevskaya  E.F. Letnikova  N.A. Kanygina  A.I. Proshenkin  N.G. Soloshenko  E.V. Vetrov  V.Yu. Kiseleva 《Russian Geology and Geophysics》2018,59(11):1433-1449

U-Pb dating of detrital zircons from the sandstones of the Mamakan Formation has been made. Geochemical and isotope parameters of the carbonate deposits of the Yanguda Formation in the Vendian-Cambrian cover of the North Muya continental block have been estimated. It has been established that only the Neoproterozoic (630-915 Ma) rocks of the North Muya block were the provenances of terrigenous material. In the least altered carbonate rocks of the Yanguda Formation, the ⁸⁷Sr/⁸⁶Sr ratio is within 0.70814-0.70879 and δ¹³C varies from -0.4 to + 1.9‰. Comparison of the evaluated isotope parameters with those of carbonate rocks of typical Vendian-Cambrian sections shows that the carbonate deposits of the Yanguda Formation accumulated in the Early Cambrian, about 520 Ma. Sedimentation of the Mamakan and Yanguda Formations took place in the local sedimentary basin in the Vendian-Early Cambrian, in the absence of tectonic activity within the North Muya block. Detrital material that formed during the destruction of the rocks of the Siberian Platform basement and cover was not supplied into the basin.  相似文献   

Dunites of the Inagli massif (Central Aldan), cumulates of lamproitic magma     

I.F. Chaika  A.E. Izokh 《Russian Geology and Geophysics》2018,59(11):1450-1460

We consider a hypothesis for the origin of PGE-bearing ultramafic rocks of the Inagli massif (Central Aldan) through fractional crystallization from ultrabasic high-potassium magma. We studied dunites and wehrlites of the Inagli massif and olivine lamproites of the Ryabinovy massif, which is also included into the Central Aldan high-potassium magmatic area. The research is focused on the chemistry of Cr-spinels and the phase composition of Cr-spinel-hosted crystallized melt inclusions and their daughter phases. Mainly two methods were used: SEM-EDS (Tescan Mira-3), to establish different phases and their relationships, and EPMA, to obtain precise chemical data on small (2-100 μm) phases. The obtained results show similarity in chromite composition and its evolutionary trends for the Inagli massif ultramafites and Ryabinovy massif lamproites. The same has been established for phlogopite and diopside from crystallized melt inclusions from the rocks of both objects. Based on the results of the study, the conclusion is drawn that the ultramafic core of the Inagli massif resulted from fractional crystallization of high-potassium melt with corresponding in composition to low-titanium lamproite. This conclusion is consistent with the previous hypotheses suggesting an ultrabasic high-potassium composition of primary melt for the Inagli ultramafites.  相似文献   

Geologic structure and correlation of the Berriasian-Lower Aptian productive beds of the Gydan Peninsula (Russian Arctic)     

S.V. Ershov  V.N. Bardachevskii  N.I. Shestakova 《Russian Geology and Geophysics》2018,59(11):1497-1507

We discuss the geologic structure of the Berriasian-Lower Aptian deposits of the Gydan Peninsula. Eight seismic sequences have been distinguished; most of them are associated with Lower Cretaceous regional clinoforms of West Siberia, their characteristics are given. A correlation of productive beds was based on the stratotype sections of the Yamal and Gydan Peninsulas as well as seismic and well data. A sequence stratigraphic model of the Berriasian-Lower Aptian complex is proposed.  相似文献   

Foundations of petroleum prediction based on the activation of geochemical processes by direct current     

V.Yu. Shigaev 《Russian Geology and Geophysics》2018,59(11):1508-1513

Petroleum prediction in local objects and the applicability of geologic environment parameters in this regard are considered. The proposed guidelines for petroleum potential prediction are based on the analysis of the distribution of typomorphic epigenetic multivalent elements loosely fixed in rocks before and after electric current treatment. The advantage of geoelectrochemical methods providing data on the chemical composition of above-productive deposits is demonstrated.  相似文献   

Natural ring structures on the Baikal ice cover: Analysis of experimental data and mathematical modeling     

N.G. Granin  I.B. Mizandrontsev  V.V. Kozlov  E.A. Tsvetova  R.Yu. Gnatovskii  V.V. Blinov  I.A. Aslamov  K.M. Kucher  V.G. Ivanov  A.A. Zhdanov 《Russian Geology and Geophysics》2018,59(11):1514-1525

Hydrophysical studies and mathematical modeling of ring structures during ice cover on Lake Baikal have shown that their existence at the stage of ice cover degradation is due to anticyclonic currents. Such currents can be generated as a result of local upwelling, which we associate with the rise of methane hydrates from the top layer of bottom sediments and their dissociation. Analysis of satellite images shows that the radii of ice rings range from 1300 to 2400 m, which is close to the baroclinic Rossby radius. The measured ice thicknesses in the area of the rings are in agreement with model calculations. Deep water renewal in Lake Baikal can also be associated with the rise of hydrates.  相似文献   

Development of medium-term prediction methods: A case study of the August 14, 2016 Onor (M_w = 5.8) earthquake on Sakhalin     

A.S. Zakupin  Yu.N. Levin  N.V. Boginskaya  O.A. Zherdeva 《Russian Geology and Geophysics》2018,59(11):1526-1532

The potential of the load-unload response ratio (LURR) method for medium-term earthquake prediction is studied for Sakhalin Island as an example. An approach to the generation of predicted conditions and assessment of their implementation in real time is considered. The results of a retrospective analysis of other large Sakhalin earthquakes are used for generalization. It is shown that deviations of prediction parameters from specified values are satisfactory for this method. It is recommended that this method be used to compile summaries of medium-term predictions for Sakhalin provided that catalogs are filled as soon as possible.  相似文献